Electrochemical Evidences for the Enhancement of Heterogeneous Electron Transfer Rates of Riboflavin in the Presence of Copper
DOI:
https://doi.org/10.3329/dujs.v62i2.21980Keywords:
Metal-Ligand interaction, Voltammetry, Heterogenous electron-transfer rate, Stability constantAbstract
Evidences for the enhancement of the heterogeneous electron transfer rates of riboflavin in the presence of copper in aqueous medium with a glassy carbon electrode were investigated by cyclic voltammetry, chronocoulometry and differential anodic stripping pulse voltammetry. It was found that copper exhibits a multi-nuclear complex with riboflavin in aqueous KCl solution. The overall stability constant of the complex was calculated (log? = 11.17), which is in a good agreement for the formation of a stable copper-riboflavin complex.
DOI: http://dx.doi.org/10.3329/dujs.v62i2.21980
Dhaka Univ. J. Sci. 62(2): 147-152, 2014 (July)
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