Carbon-Hydrogen Bond Activation of Phenyldi(2- Thienyl)Phosphine at A Triruthenium Cluster Center

Authors

  • Shahed Rana Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342
  • Shishir Ghosh Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342
  • Shariff E Kabir Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342

DOI:

https://doi.org/10.3329/jbcs.v25i1.11764

Keywords:

Triruthenium, Cluster

Abstract

Ketyl-initiated reaction between Ru3(CO)12 and phenyldi(2-thienyl)phosphine (PhPTh2) furnished simple phosphine-substituted triruthenium clusters [Ru3(CO)10(PhPTh2)21 and [Ru3(CO)9(PhPTh2)3] 2. Heating 1 in boiling benzene afforded [Ru3(CO)8{?3- PhThP(C4H2S)}(PhPTh2)] 3 by carbon-hydrogen bond cleavage of a coordinated thienylphosphine ligand. All three new clusters have been characterized by elemental analysis, IR and NMR spectroscopic data.

DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11764

Journal of Bangladesh Chemical Society, Vol. 25(1), 1-6, 2012

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Published

2012-09-02

How to Cite

Rana, S., Ghosh, S., & Kabir, S. E. (2012). Carbon-Hydrogen Bond Activation of Phenyldi(2- Thienyl)Phosphine at A Triruthenium Cluster Center. Journal of the Bangladesh Chemical Society, 25(1), 1–6. https://doi.org/10.3329/jbcs.v25i1.11764

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Articles