Binuclear Rhenium and Manganese Carbonyl Compounds Containing Hetero-Mercaptanes

Authors

  • Md Anwarul Hoque Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342
  • Md Arzu Miah Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342
  • md Nurul Abser Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342
  • Abul K Azad Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342
  • Kamrun N Khan Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342
  • Md Manzurul Karim Department of Chemistry, Jahangirnagar University, Savar, Dhaka-1342

DOI:

https://doi.org/10.3329/jbcs.v25i1.11775

Keywords:

Carbonyl, Compounds

Abstract

Treatment of 2-Mercaptothiazoline, 2-Mercaptobenzimidazole, 2-Mercapto-1- methylimidazole with [M2(CO)10] (M = Re and Mn) at ambient temperature in presence of decarbonylating reagent Me3NO give the complexes [Mn2(?-?2-C3H4NS2)2(CO)6] (1), [Re2(?-?2-C3H4NS2)2(CO)6] (2), [Mn2(?-?2-C7H5SN2)2(CO)6] (3), [Re2(?-?2- C7H5SN2)2(CO)6] (4), [Re2(?-?2-C4H5N2S)2(CO)6] (5) and [Re2(?1-C4H5N2SH)(CO)9] (6) respectively. All the compounds have been characterized by IR, 1H NMR and mass spectral data. The heterocyclic ligands are expected to be coordinated to two or single metal atom through the nitrogen and sulfur atoms or via only sulfur atom.

DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11775

Journal of Bangladesh Chemical Society, Vol. 25(1), 62-70, 2012>

 

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Published

2012-09-03

How to Cite

Hoque, M. A., Miah, M. A., Abser, md N., Azad, A. K., Khan, K. N., & Karim, M. M. (2012). Binuclear Rhenium and Manganese Carbonyl Compounds Containing Hetero-Mercaptanes. Journal of the Bangladesh Chemical Society, 25(1), 62–70. https://doi.org/10.3329/jbcs.v25i1.11775

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