Synthesis of N-(2'-imidazolyl)-2- aminopyridyl Palladium Dichloride and its application as catalyst in Suzuki-Miyaura cross coupling reaction

Authors

  • Md Abul Hashem Department of Chemistry, Jahangirnagar University, Savar, Dhaka
  • Abeda Sultana Department of Chemistry, Jahangirnagar University, Savar, Dhaka

DOI:

https://doi.org/10.3329/jbcs.v24i2.9701

Keywords:

N-(2'-imidazolyl)-2-aminopyridine ligand, Palladium Complexes, Palladacycles, Suzuki-Miyaura Cross Coupling, Biaryls, Terphenyls, Heterobiaryls, Suzuki-reaction

Abstract

The ligand N-(2′-imidazolyl)-2- aminopyridine 9 was prepared from imidazole. Compound 9 forms complex with Na2PdCl4 in methanol. The complex 10 (1.5 mmol %) was utilized in Suzuki-Miyaura cross-coupling reaction to prepare substituted biphenyls, terphenyls, and heterobiaryls in good to excellent yields.

Keywords: N-(2′-imidazolyl)-2-aminopyridine ligand; Palladium Complexes; Palladacycles; Suzuki-Miyaura Cross Coupling; Biaryls; Terphenyls; Heterobiaryls; Suzuki-reaction.

DOI: http://dx.doi.org/10.3329/jbcs.v24i2.9701

Journal of Bangladesh Chemical Society, Vol. 24(2), 123-134, 2011

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How to Cite

Hashem, M. A., & Sultana, A. (2012). Synthesis of N-(2’-imidazolyl)-2- aminopyridyl Palladium Dichloride and its application as catalyst in Suzuki-Miyaura cross coupling reaction. Journal of the Bangladesh Chemical Society, 24(2), 123–134. https://doi.org/10.3329/jbcs.v24i2.9701

Issue

Vol. 24 No. 2 (2011)

Section

Articles