Polymetallic Complexes Part 91 Dimeric and Monomeric Complexes of Co<sup>II</sup>, Ni<sup>II</sup>, Cu<sup>II</sup>, Zn<sup>II</sup>, Cd<sup>II</sup> and Hg<sup>II</sup> with N&cap;O-O&cap;N and N&cap;O Donor Bis-bidentate and Bi-dentate Azodye Ligands

Authors

  • Bi B Mahapatra P.G. Department of Chemistry, G.M. Autonomous College, Sambalpur
  • AK Sarangi P.G. Department of Chemistry, G.M. Autonomous College, Sambalpur

DOI:

https://doi.org/10.3329/bjsir.v46i2.3558

Keywords:

Polymetallic complexes, Azodye complexes, Multidentate ligands

Abstract

Bis-bidentate azodye, 4,4 / -bis (4/ -dihydroxyquinolincazo)3,3/ -dimethoxydibenzene having N∩O-O∩N donors and bidentate azodye (4 -hyoxyquinolineazo)4/ methoxybenzene having N∩O donors form dimeric and monomeric complexes of the type [M2LCl2(H2O)6], [M/2LCl2(H2O)2], [ML/2(H2O)2] and [M/L/2] where M = CoII, NiII, CuII; M /II, CdII, HgII. The complexes of the first and third categories are found to be six-coordinated with an octahedral and distorted octahedral configuration and the complexes of second and fourth type are four-coordinated with a tetrahedral geometry around the metal ions. The complexes have been characterised based upon analytical, conductance, magnetic susceptibility, i.r., electronic spectra, N.M.R., E.S.R. and X-ray diffraction data. The unit cell parameters like a, b, c, α, ß, γ and V (volume) have been calculated from the 2θ values. The unit cell geometry of the complex [Co2LCl2(H2O)6] is found to be monoclinic.

Key words: Polymetallic complexes; Azodye complexes; Multidentate ligands.

DOI: http://dx.doi.org/10.3329/bjsir.v46i2.3558

Bangladesh J. Sci. Ind. Res. 46(2), 259-264, 2011

Downloads

Download data is not yet available.
Abstract
118
PDF
84

Downloads

Published

2011-08-09

How to Cite

Mahapatra, B. B., & Sarangi, A. (2011). Polymetallic Complexes Part 91 Dimeric and Monomeric Complexes of Co<sup>II</sup>, Ni<sup>II</sup>, Cu<sup>II</sup>, Zn<sup>II</sup>, Cd<sup>II</sup> and Hg<sup>II</sup> with N&cap;O-O&cap;N and N&cap;O Donor Bis-bidentate and Bi-dentate Azodye Ligands. Bangladesh Journal of Scientific and Industrial Research, 46(2), 259–264. https://doi.org/10.3329/bjsir.v46i2.3558

Issue

Section

Articles