Polymetallic Complexes Part LXXXXV Bis-bidentate Donor Azodye Dimeric Complexes

Authors

  • Bipin Bihari Mahapatra Department of Chemistry, G.M. College, Sambalpur, Orissa
  • Nilanchala Patel Department of Chemistry, G.M. College, Sambalpur, Orissa

DOI:

https://doi.org/10.3329/bjsir.v44i4.4596

Keywords:

Polymetallic complexes, Azodye complexes, Multidentate ligands

Abstract

Twelve dimeric complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with two new bis-bidentate donor azodye ligands, 4,4'-bis (2'-hydroxy-3',5'-dinitrophenylazo) diphenylsulphone and 4,4'-bis (2'-hydroxy-5'-nitrophenylazo) diphenylsulphone has been synthesized. The structure elucidation of the complexes was made basing upon analytical, conductance, magnetic susceptibility, IR, electronic spectra, ESR, NMR, and X-ray diffraction (powder pattern) data. Antifungal activities of the ligands and a few complexes were also studied. The cobalt (II) and nickel (II) complexes are found to be octahedral, copper (II) complexes are distorted octahedral and a tetrahedral stereochemistry has been suggested to Zn (II), Cd (II) and Hg (II) complexes.

Key words: Polymetallic complexes; Azodye complexes; Multidentate ligands.

DOI: 10.3329/bjsir.v44i4.4596

Bangladesh J. Sci. Ind. Res. 44(4), 445-452, 2009

Downloads

Download data is not yet available.
Abstract
86
PDF
86

Downloads

How to Cite

Mahapatra, B. B., & Patel, N. (2010). Polymetallic Complexes Part LXXXXV Bis-bidentate Donor Azodye Dimeric Complexes. Bangladesh Journal of Scientific and Industrial Research, 44(4), 445–452. https://doi.org/10.3329/bjsir.v44i4.4596

Issue

Vol. 44 No. 4 (2009)

Section

Articles

License

Bangladesh Council of Scientific and Industrial Research (BCSIR) holds the copyright to all contents published in Bangladesh Journal of Scientific and Industrial Research (BJSIR). A copyright transfer form should be signed by the author(s) and be returned to BJSIR.

The entire contents of the BJSIR are protected under Bangladesh Council of Scientific and Industrial Research (BCSIR) copyrights.

Creative Commons Licence
BJSIR is an open access journal, and articles are distributed under the terms of the Creative Commons Attribution-NonCommercial License (CC BY-NC) Creative Commons Attribution-NonCommercial 4.0 International License which allows others remix, tweak, and build upon the articles non-commercially, and although their new works must also acknowledge and be non-commercial, they don’t have to license their derivative works on the same terms.