Experimental design modelling for the extraction of vanadium(IV) extraction V(IV)-SO<sub>4</sub> <sup>2-</sup> (H+, Na+)-Cyanex 301-kerosene system

Authors

  • AK Karmakar Department of Applied Chemistry and Chemical Engineering, Rajshahi University, Rajshahi-6205, Bangladesh
  • RK Biswas Department of Applied Chemistry and Chemical Engineering, Rajshahi University, Rajshahi-6205, Bangladesh

DOI:

https://doi.org/10.3329/bjsir.v56i2.54316

Keywords:

Extraction; Cyanex 301; Vanadium(IV); Factorial design; Sulphate; Kerosene

Abstract

The vanadium(IV) extraction from acidic sulphate medium by Cyanex 301 (bis-(2,4,4-trimethylpentyl) dithiophosphinic acid) dissolved in kerosene is explored from the modelling point of view. The time of equilibration is only 10 min and above pH(eq) = 2, high extraction (>90%) occurs.On keeping organic to aqueous phase ratio of 1, factors affecting the extent of extraction (log D and log CD) are pH(eq), [V(IV)],[SO4 2-], [Cyanex 301]and temperature (T). The high (+) and low (-) levels are considered for the factors. The 25 factorial design is used to find the regression equation for the V(IV) extraction by Cyanex 301. On symbolizing pH(eq), log [V(IV)], , log [SO4 2-], log [Cyanex 301], and 1/T (K-1); where concentration terms are in mol/L, as P , M, S,E, and (1/T), respectively,the regression equation obtained is: log CD = 1.95 - 0.23 M + 1.83 P + 2.07 E + 0.84 S - (888.9/T) - 0.26 PS.The current system shows only the interaction effect among pH(eq) and [SO4 2-]. The equation can well describe the system,and it can be used to optimize factors for satisfactory extraction.

Bangladesh J. Sci. Ind. Res.56(2), 95-104, 2021

Downloads

Download data is not yet available.
Abstract
35
PDF
34

Downloads

Published

2021-06-23

How to Cite

Karmakar, A., & Biswas, R. (2021). Experimental design modelling for the extraction of vanadium(IV) extraction V(IV)-SO<sub>4</sub> <sup>2-</sup> (H+, Na+)-Cyanex 301-kerosene system. Bangladesh Journal of Scientific and Industrial Research, 56(2), 95–104. https://doi.org/10.3329/bjsir.v56i2.54316

Issue

Vol. 56 No. 2 (2021)

Section

Articles

License

Bangladesh Council of Scientific and Industrial Research (BCSIR) holds the copyright to all contents published in Bangladesh Journal of Scientific and Industrial Research (BJSIR). A copyright transfer form should be signed by the author(s) and be returned to BJSIR.

The entire contents of the BJSIR are protected under Bangladesh Council of Scientific and Industrial Research (BCSIR) copyrights.

Creative Commons Licence
BJSIR is an open access journal, and articles are distributed under the terms of the Creative Commons Attribution-NonCommercial License (CC BY-NC) Creative Commons Attribution-NonCommercial 4.0 International License which allows others remix, tweak, and build upon the articles non-commercially, and although their new works must also acknowledge and be non-commercial, they don’t have to license their derivative works on the same terms.