Synthesis and Evaluation of L-glutamide Derived Carbonyl Group Containing RP-HPLC Phase for Polycyclic Aromatic Hydrocarbon (PAH) Separation

Authors

  • AA Rana Department of Applied Chemistry & Chemical Engineering, University of Dhaka, Dhaka
  • M Kamruzzaman Department of Applied Chemistry & Chemical Engineering, University of Dhaka, Dhaka
  • M Takafuji Department of Applied Chemistry & Biochemistry, Kumamoto University, Kurokami, Kumamoto

DOI:

https://doi.org/10.3329/bjsir.v46i3.9031

Keywords:

L-glutamide lipid, RP-HPLC, Enhance selectivity, Polycyclic aromatic hydrocarbons

Abstract

A new L-glutamide derived internal C=O group containing HPLC stationary phase was synthesized. The L-glutamide lipid was immobilized on to silica surface through aminopropyltrimethoxysilane (APS) linker. The detailed chemical structure of the compounds leading to the final lipid was characterized by melting point measurement, FTIR, 1H NMR and elemental analysis in each step. Chromatographic properties of silica immobilized N-(pyrinylbutyric) L-glutamic acid, Sil-PBG, were evaluated under reversed phase conditions by separation of different polycyclic aromatic hydrocarbons (PAHs) and the results were then compared with monomeric octadecylated silica stationary phase (ODS). Chromatographic evaluation of the new phase showed promising results for the separation of PAHs.

Key words: L-glutamide lipid; RP-HPLC; Enhance selectivity; Polycyclic aromatic hydrocarbons

DOI: http://dx.doi.org/10.3329/bjsir.v46i3.9031

BJSIR 2011; 46(3): 271-276

Downloads

Download data is not yet available.
Abstract
121
PDF
95

Downloads

How to Cite

Rana, A., Kamruzzaman, M., & Takafuji, M. (2011). Synthesis and Evaluation of L-glutamide Derived Carbonyl Group Containing RP-HPLC Phase for Polycyclic Aromatic Hydrocarbon (PAH) Separation. Bangladesh Journal of Scientific and Industrial Research, 46(3), 271–276. https://doi.org/10.3329/bjsir.v46i3.9031

Issue

Vol. 46 No. 3 (2011)

Section

Articles

License

Bangladesh Council of Scientific and Industrial Research (BCSIR) holds the copyright to all contents published in Bangladesh Journal of Scientific and Industrial Research (BJSIR). A copyright transfer form should be signed by the author(s) and be returned to BJSIR.

The entire contents of the BJSIR are protected under Bangladesh Council of Scientific and Industrial Research (BCSIR) copyrights.

Creative Commons Licence
BJSIR is an open access journal, and articles are distributed under the terms of the Creative Commons Attribution-NonCommercial License (CC BY-NC) Creative Commons Attribution-NonCommercial 4.0 International License which allows others remix, tweak, and build upon the articles non-commercially, and although their new works must also acknowledge and be non-commercial, they don’t have to license their derivative works on the same terms.