Volumetric and viscometric studies on electrolytes in non-aqueous solvent

Authors

  • MA Yousuf Department of Chemistry, Khulna University of Engineering and Technology, Khulna
  • KM Salim Reza Department of Chemistry, Khulna University of Engineering and Technology, Khulna
  • Md Moniruzzaman Department of Chemistry, Khulna University of Engineering and Technology, Khulna
  • MA Aziz Department of Chemistry, Khulna University of Engineering and Technology, Khulna
  • MA Salam Department of Chemistry, University of Dhaka, Dhaka

Keywords:

Density, Apparent and partial molal volume, viscosity coefficient

Abstract

The densities, ρ and viscosities, η of NH4Cl, NiCl2 and FeCl3 in dimethylsulfoxide were studied as a function of concentration. The partial molal volume, (φ0v) of these electrolytes were evaluated. The viscosity and viscosity-coefficients (A and B) were also determined by Jones-Dole equation. B-coefficient for NiCl2 and FeCl3 are positive that show structure making behavior in all the solutions while those of NH4Cl are negative indicating structure breaking properties. The coefficient A represents the solute-solute interactions coupled with size and shape effect of the solute and to some extent solute-solvent interactions. The behaviors of three solutes in binary systems were discussed in terms of the charge, size and hydrogen bonding effect.

Keywords: Density, Apparent and partial molal volume, viscosity coefficient.

DOI: 10.3329/diujst.v4i2.4360

Daffodil International University Journal of Science and Technology Vol.4(2) 2009 pp.15-18

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Volumetric and viscometric studies on electrolytes in non-aqueous solvent. (2010). Daffodil International University Journal of Science and Technology, 4(2), 15-18. https://doi.org/10.3329/diujst.v4i2.4360

Issue

Vol. 4 No. 2 (2009)

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Papers

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How to Cite

Volumetric and viscometric studies on electrolytes in non-aqueous solvent. (2010). Daffodil International University Journal of Science and Technology, 4(2), 15-18. https://doi.org/10.3329/diujst.v4i2.4360