Electrochemical sensing of nitrate ions at Cu-immobilized gold electrode in neutral medium

Authors

  • Abrar Yasir Abir Department of Chemistry, Pabna University of Science and Technology, Pabna, Bangladesh.
  • Ishmam Ibnul Arabi Department of Natural Science, Port City International University, Chattogram, Bangladesh.
  • Nusrat Jahan Mousumi Department of Textile Engineering, Green University of Bangladesh, Dhaka, Bangladesh
  • Mohammad Shariful Alam Department of Textile Engineering, Green University of Bangladesh, Dhaka, Bangladesh
  • Md Faruak Ahmad Department of Chemistry, Pabna University of Science and Technology, Pabna, Bangladesh.
  • Mohammad Abul Hasnat Department of Chemistry, Shahjalal University of Science and Technology, Sylhet, Bangladesh.

DOI:

https://doi.org/10.3329/gubjse.v10i1.74948

Keywords:

Nitrate reduction, Environmental safety, Electrocatalyst, Sensor

Abstract

The Cu-immobilized Au surface was electro-catalytically employed for nitrate ions reduction in a neutral solution. According to cyclic voltammetric studies, the Cu/Au electrode has an improved electro-catalytic impact on converting nitrate ions into nitrite ions, governed by a two-electron transfer system. This modified electrode demonstrated good performance in real sample analysis along with good sensitivity (3.2518 $ \mu A \mu M^{-1} cm^{-2}$), long linear detection range (1.2 to 111.4 $\mu M$), a very lower limit of detection (0.85 $\mu M$), an excellent reproducibility. Thus, to determine nitrate ions in an aqueous media, an electrochemical sensor based on a Cu/Au electrode is suggested.

GUB JOURNAL OF SCIENCE AND ENGINEERING, Vol 10(1), 2023 P 75-85

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Published

2024-07-15

How to Cite

Abir, A. Y., Ishmam Ibnul Arabi, Mousumi, N. J., Alam, M. S., Ahmad, M. F., & Hasnat, M. A. (2024). Electrochemical sensing of nitrate ions at Cu-immobilized gold electrode in neutral medium. GUB Journal of Science and Engineering, 10(1), 75–85. https://doi.org/10.3329/gubjse.v10i1.74948

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