Synthesis, Spectroscopic Characterization and Theoretical Study of Schiff Bases Derived from Phenylsulfonylamide

Authors

  • J. S. Hadi Department of Chemistry, College of Education, University of Basrah, Basrah, Iraq
  • B. K. Alsalam Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq
  • A.H. Essa Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

DOI:

https://doi.org/10.3329/jsr.v1i3.2589

Keywords:

Sulphoacetamide sodium complex, Schiff bases, Sulpha drug, Semi-empirical (PM3) methods.

Abstract

The synthesis, characterization, and theoretical study of two Schiff bases of ligands derived from condensation of sulphoacetamide sodium with 4-methoxy benzaldehyde and salicalaldehyde arereported. Spectroscopic techniques, including IR, UV, 1H NMR, and CHN analysis were used to identify the product. The calculated HOMO is largely localized on the N-benzylideneaniline fragment, while the calculated LUMO of the studied molecule is seen to be substantially localized along the C–C axis of the conjugated system.

 

Keyword: Sulphoacetamide sodium complex; Schiff bases; Sulpha drug; Semi-empirical (PM3) methods.

 

© 2009 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.

 

 

DOI: 10.3329/jsr.v1i3.2589            J. Sci. Res. 1 (3), 563-568 (2009)

 

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Author Biographies

J. S. Hadi, Department of Chemistry, College of Education, University of Basrah, Basrah, Iraq

J. S. Hadi 

Department of Chemistry, College of Education, University of Basrah, Basrah, Iraq

 

B. K. Alsalam, Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

B. K. Alsalami

 

Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq


A.H. Essa, Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

Ali Hashem Essa

 

Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq


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Published

2009-08-29

How to Cite

Hadi, J. S., Alsalam, B. K., & Essa, A. (2009). Synthesis, Spectroscopic Characterization and Theoretical Study of Schiff Bases Derived from Phenylsulfonylamide. Journal of Scientific Research, 1(3), 563–568. https://doi.org/10.3329/jsr.v1i3.2589

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Section

Section B: Chemical and Biological Sciences