Synthesis and Study of Charge-transfer Complexes for 5,6-dimethyl-2,1,3-benzoselenadiazole

Authors

  • A. F. Hassan Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq
  • H. A. Radhy Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq
  • A. H. Essa Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

DOI:

https://doi.org/10.3329/jsr.v1i3.2590

Keywords:

Charge transfer complexes, Dimethylbenzoselnadiazoles, Naphthaquinone, Dihydroxyanthraquinone, Hydroxynaphthaquinone, Dichlorodicyanobenzoquinone (DDQ), Semi-empirical (PM3) methods.

Abstract

The synthesis of new solid charge-transfer (CT) complexes using 5,6-dimethyl-2,1,3-benzoselnadiazoles as donors with 1,4-naphthaquinone; 1,8-dihydroxyanthraquinone, 2-hydroxy-1,4-naphthaquinone and 2,3-dichloro-4,5-dicyano-p-benzoquinone (DDQ) as acceptor are reported. These complexes are characterized by elemental analysis, IR, UV-V, and 1HNMR spectroscopic data. Solid conductivity for 1, 2 and 3 compounds revel that they are not conductors. The calculated HOMO is largely localized on the selnadiazoles fragment, while the calculated LUMO of the studied molecule is seen to be substantially localized along the C–C axis of the conjugated system.

 

Keywords: Charge transfer complexes; Dimethylbenzoselnadiazoles; Naphthaquinone; Dihydroxyanthraquinone; Hydroxynaphthaquinone; Dichlorodicyanobenzoquinone (DDQ); Semi-empirical (PM3) methods.

 

© 2009 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.

 

 

DOI: 10.3329/jsr.v1i3.2590              J. Sci. Res. 1 (3), 569-575 (2009)

 

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Author Biographies

A. F. Hassan, Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

Attard F. Hassan

Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

H. A. Radhy, Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

Hanan A. Radhy

Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

 

alihashemalyunis@yahoo.com


A. H. Essa, Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

Ali Hashem Essa

Department of Chemistry, College of Science, University of Basrah, Basrah, Iraq

 

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Published

2009-08-29

How to Cite

Hassan, A. F., Radhy, H. A., & Essa, A. H. (2009). Synthesis and Study of Charge-transfer Complexes for 5,6-dimethyl-2,1,3-benzoselenadiazole. Journal of Scientific Research, 1(3), 569–575. https://doi.org/10.3329/jsr.v1i3.2590

Issue

Vol. 1 No. 3 (2009)

Section

Section B: Chemical and Biological Sciences

License

© Journal of Scientific Research

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