Greener Protocol for the Synthesis of Carbamates

Authors

  • A. Satheesh Department of Chemistry, Centurion University of Technology and Management, Vizianagram (Andhra Pradesh), India
  • H. Usha Department of Chemistry, Govt. Polytechnic for Women, Srikakulam (Andhra Pradesh), India
  • D. S. Priya Department of Chemistry, Govt. Degree College for Men, Srikakulam (Andhra Pradesh), India
  • A. V. L. N. H. Hariharan Department of Chemistry, GITAM University, Rushikonda, Visakhapatnam. Andhra Pradesh, India
  • M. V. V. Ramanjaneyulu Department of Chemistry, KGRL (A) College, Bhimavaram, West Godavari (Andhra Pradesh), India

DOI:

https://doi.org/10.3329/jsr.v15i2.60649

Abstract

An efficient and environmentally friendly protocol has been developed for synthesizing carbamates. Carbamate derivatives are frequently used as pesticides (insecticides, fungicides, and herbicides), as starting materials in producing paints and polyurethanes, and as protecting groups of amines in organic synthesis. It is a simple and solvent-free methodology to prepare primary carbamates in high yield and purity from compounds sodium cyanate, Phenol/alcohol, and TCA (Trichloro acetic acid). We reported the application of TCA as a mild, convenient and effective reagent for this transformation.

 

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Published

2023-05-01

How to Cite

Satheesh, A. ., Usha , H. ., Priya, D. S. ., Hariharan, A. V. L. N. H. ., & Ramanjaneyulu, M. V. V. . (2023). Greener Protocol for the Synthesis of Carbamates. Journal of Scientific Research, 15(2), 481–488. https://doi.org/10.3329/jsr.v15i2.60649

Issue

Section

Section B: Chemical and Biological Sciences