2D ZIF-L(Zn) for Hybrid Copolymerization of Methyl Methacrylate and ε-Caprolactone under Solvent-free Medium

Authors

  • F. Yasmn Department of Chemistry, Mawlana Bhashani Science and Technology University, Santosh, Tangail-1902, Bangladesh
  • M. A. Rahaman Department of Chemistry, Mawlana Bhashani Science and Technology University, Santosh, Tangail-1902, Bangladesh

DOI:

https://doi.org/10.3329/jsr.v16i1.65039

Abstract

Herein, we report the hybrid copolymerization of methyl methacrylate (MMA) and ε-caprolactone (CL). 2D metal-organic frameworks, ZIF-L as a robust polymerization catalyst, can catalyze this hybrid copolymerization. Though these monomers differ from each other in structure and activity, different characterization techniques (1H-NMR, 13C-NMR, GPC, DSC, fractional precipitation techniques) confirm that they form biodegradable block copolymer PMMA-b-PCL with high molecular weight (1190 kg/mol). Also, PXRD and SEM results of the recovered ZIF-L reveal that the catalyst ZIF-L is remarkably stable even after a long-time polymerization reaction with no significant loss in activity.

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Published

2024-01-01

How to Cite

Yasmn, F., & Rahaman , M. A. (2024). 2D ZIF-L(Zn) for Hybrid Copolymerization of Methyl Methacrylate and ε-Caprolactone under Solvent-free Medium. Journal of Scientific Research, 16(1), 253–264. https://doi.org/10.3329/jsr.v16i1.65039

Issue

Vol. 16 No. 1 (2024)

Section

Section B: Chemical and Biological Sciences

License

Creative Commons License

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© Journal of Scientific Research

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Articles published in the "Journal of Scientific Research" are Open Access articles under a Creative Commons Attribution-ShareAlike 4.0 International license (CC BY-SA 4.0). This license permits use, distribution and reproduction in any medium, provided the original work is properly cited and initial publication in this journal. In addition to that, users must provide a link to the license, indicate if changes are made and distribute using the same license as original if the original content has been remixed, transformed or built upon.