Volumetric and Viscometric Studies of Binary Mixtures of Ethyl Acetate with n-Propanol and 2-Propanol at T= (303.15, 308.15, 313.15, and 318.15) K under Atmospheric Pressure

Authors

  • J. Alauddin Department of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia – 7003, Bangladesh
  • S. Pande Department of Chemistry, Jashore University of Science and Technology, Jashore – 7408, Bangladesh
  • S. Alauddin Statistics Discipline, Khulna University, Khulna-9208, Bangladesh
  • M. H. Uddin Department of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia – 7003, Bangladesh
  • S. M. Al-Reza Department of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia – 7003, Bangladesh

DOI:

https://doi.org/10.3329/jsr.v17i3.79608

Abstract

In this study, densities and viscosities of binary mixtures formed by ethyl acetate with n-propanol and 2-propanol have been measured over the entire range of composition at T = (303.15, 308.15, 313.15, and 318.15) K under atmospheric pressure. Excess molar volume, VE, deviation in viscosity,    and excess Gibb’s free energy of activation of viscous flow,  have been calculated from experimental density and viscosity data. The computed excess functions have been fitted to Redlich-Kister polynomial equation. The observed values of excess properties for both the systems have been interpreted in terms of molecular interaction in the mixtures. Results show that for both mixtures, the chemical or specific interactions between ethyl acetate and alcohol molecules are absent, and dispersion type forces are predominant.

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Published

2025-09-01

How to Cite

Alauddin, J., Pande, S., Alauddin, S., Uddin, M. H., & Al-Reza, S. M. (2025). Volumetric and Viscometric Studies of Binary Mixtures of Ethyl Acetate with n-Propanol and 2-Propanol at T= (303.15, 308.15, 313.15, and 318.15) K under Atmospheric Pressure. Journal of Scientific Research, 17(3), 937–949. https://doi.org/10.3329/jsr.v17i3.79608

Issue

Vol. 17 No. 3 (2025)

Section

Section B: Chemical and Biological Sciences

License

Creative Commons License

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© Journal of Scientific Research

Creative Commons License

Articles published in the "Journal of Scientific Research" are Open Access articles under a Creative Commons Attribution-ShareAlike 4.0 International license (CC BY-SA 4.0). This license permits use, distribution and reproduction in any medium, provided the original work is properly cited and initial publication in this journal. In addition to that, users must provide a link to the license, indicate if changes are made and distribute using the same license as original if the original content has been remixed, transformed or built upon.