Structural Evaluation and Antibacterial Sensitivity of Iron (III) Complexes of 4-<i>n</i>-hexyloxybenzoylhydrazine with Some Aliphatic and Aromatic

Authors

  • M. Al-Amin-Al-Azadul Islam Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi-6204
  • M. A. Mumit Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi-6204
  • T. K. Pal Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi-6204
  • M. A. Alam Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi-6204

DOI:

https://doi.org/10.3329/jsr.v4i3.9807

Keywords:

4-n-hexyloxybenzoylhydrazine, Thermogravimetric analyses, Antibacterial activity, Aroylhydrazones.

Abstract

The condensation reaction of N-alkylidene or N-arylidene-(4-n-hexyloxy)benzoylhydrazone [L] (1-7) where, R= formaldehyde (1), acetaldehyde (2), butyraldehyde (3), cinnamaldehyde (4), 4-N,N-dimethylaminobenzaldehyde (5), 2-hydroxybenzaldehyde (6) and 4-methoxybenzaldehyde (7) with Fe(III) chloride hexahydrate afforded octahedral (8-9) [Fe(L3).nH2O] and square-pyramidal (10-14) [Fe(L2)Cl.nH2O] complexes. The complexes (8-10) were obtained in presence of pyridine and the complexes (11-14) were obtained by the direct reaction of the Schiffs bases with Fe3+ ion. The complexes were characterized by magnetic moment measurement, UV-visible, infrared, 1H-NMR and TGA (Thermo gravimetric analysis)  studies. The Schiffs bases containing small alkyl group at the hydrazine moiety formed octahedral complexes, while the bulky/aryl/substituted aryl moiety, yielded five coordinated square-pyramidal complexes. The complexes were found to be quite stable and decomposition of the complexes ended with ferric oxide as final product. Complexes (10) and (13) showed no activity against all the bacteria. Complexes (8), (9) and (12) showed resistance while the complex (14) manifested intermediate antibacterial activity.

© 2012 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.

doi: http://dx.doi.org/10.3329/jsr.v4i3.9807 J. Sci. Res. 4 (3), 635-64 (2012)

Downloads

Download data is not yet available.
Abstract
164
PDF
98

Author Biography

M. A. Alam, Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi-6204

 


Downloads

Published

2012-08-27

How to Cite

Islam, M. A.-A.-A.-A., Mumit, M. A., Pal, T. K., & Alam, M. A. (2012). Structural Evaluation and Antibacterial Sensitivity of Iron (III) Complexes of 4-<i>n</i>-hexyloxybenzoylhydrazine with Some Aliphatic and Aromatic. Journal of Scientific Research, 4(3), 635–647. https://doi.org/10.3329/jsr.v4i3.9807

Issue

Vol. 4 No. 3 (2012)

Section

Section B: Chemical and Biological Sciences

License

© Journal of Scientific Research

Creative Commons License

Articles published in the "Journal of Scientific Research" are Open Access articles under a Creative Commons Attribution-ShareAlike 4.0 International license (CC BY-SA 4.0). This license permits use, distribution and reproduction in any medium, provided the original work is properly cited and initial publication in this journal. In addition to that, users must provide a link to the license, indicate if changes are made and distribute using the same license as original if the original content has been remixed, transformed or built upon.