Synthesis, characterization and Electrochemical studies of Ferrocenyl-2, 4-Dinitrophenylhydrazone

Authors

  • Tahmina Sultana Department of Chemistry, Shahjalal University of Science & Technology, Sylhet-3114
  • Chowdhury A Waheed Department of Chemistry, Shahjalal University of Science & Technology, Sylhet-3114
  • SM Saiful Islam Department of Chemistry, Shahjalal University of Science & Technology, Sylhet-3114
  • Abu Ali Ibn Sina Department of Chemistry, Shahjalal University of Science & Technology, Sylhet-3114
  • Muhammad Younus Department of Chemistry, Shahjalal University of Science & Technology, Sylhet-3114
  • Md Abdul Jabbar Department of Chemistry, University of Dhaka, Dhaka-1000
  • Md Riad Hossain Sabuj Department of Chemistry, University of Dhaka, Dhaka-1000

DOI:

https://doi.org/10.3329/jbas.v38i2.21342

Keywords:

Synthesis, Ferrocenenyl imine, Characterization, Electrochemical

Abstract

A ferrocenyl imine complex, Fc-C(CH3)=N-NH-C6H3-2,4-(NO2)2 (Fc = ferrocenyl) has been synthesized by the condensation reaction between acetylferrocene and 2,4-dinitrophenyl hydrazine. The compound was synthesised previously, and characterized by IR, 1H and elemental analysis. It was further characterized by 13C {1H} NMR spectroscopy and mass spectrometry. The redox property of the complex was studied by cyclic voltammetry, differential pulse voltammetry and chronocoulometry. The redox process of the complex was found to be reversible at a platinum-disc electrode, and the redox potential of the imine complex was shifted to more anodic position with respect to ferrocene. The redox reactivity of the complex was enhanced in the presence of oxygen.

DOI: http://dx.doi.org/10.3329/jbas.v38i2.21342

Journal of Bangladesh Academy of Sciences, Vol. 38, No. 2, 177-187, 2014

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Published

2014-12-28

How to Cite

Sultana, T., Waheed, C. A., Islam, S. S., Sina, A. A. I., Younus, M., Jabbar, M. A., & Sabuj, M. R. H. (2014). Synthesis, characterization and Electrochemical studies of Ferrocenyl-2, 4-Dinitrophenylhydrazone. Journal of Bangladesh Academy of Sciences, 38(2), 177–187. https://doi.org/10.3329/jbas.v38i2.21342

Issue

Vol. 38 No. 2 (2014)

Section

Articles