Conjugated Platinum-Poly-Ynes with extended Arylene Ethynylenes

Authors

  • Masnun Naher Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114
  • Shawon Shahriar Mehdi Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114
  • Muhammad Kausar Ahmed Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114
  • Muhammad Mostafijur Rahman Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114
  • Mohammad Mizanur Rahman Khan Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114
  • Muhammad Younus Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114

DOI:

https://doi.org/10.3329/jbas.v39i2.25952

Keywords:

Platinum-poly-yne polymer, Conjugated organic polymer, Hay’s oxidative coupling, Condensation

Abstract

The platinum-poly-yne polymers poly[trans-bis(tri-n-butylphosphine) platinum-poly (4,4´- diethynylenearylene)] (arylene = biphenylene 3 and anthracene 4) were synthesized by the condensation reaction between poly(diethynylenearylene) (arylene = biphenylene 1 and anthracene 2) and trans-[(PnBu3)2PtCl2] in diisopropyl amine and dichloromethane under nitrogen atmosphere in the presence of CuI catalyst. The newly synthesized platinum containing poly-yne polymers exhibit good solubility in common organic solvents. These metal linked polymers were characterized by IR, 1H NMR and 31P NMR spectroscopy.

Journal of Bangladesh Academy of Sciences, Vol. 39, No. 2, 195-202, 2015

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Author Biography

Masnun Naher, Department of Chemistry, Shahjalal University of Science and Technology, Sylhet-3114



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Published

2015-12-14

How to Cite

Naher, M., Mehdi, S. S., Ahmed, M. K., Rahman, M. M., Khan, M. M. R., & Younus, M. (2015). Conjugated Platinum-Poly-Ynes with extended Arylene Ethynylenes. Journal of Bangladesh Academy of Sciences, 39(2), 195–202. https://doi.org/10.3329/jbas.v39i2.25952

Issue

Vol. 39 No. 2 (2015)

Section

Articles